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Synlett 2010(10): 1572-1573
DOI: 10.1055/s-0029-1219938
DOI: 10.1055/s-0029-1219938
SPOTLIGHT
© Georg Thieme Verlag
Stuttgart ˙ New York
Thiocarbonylthio Compounds
Further Information
Publication History
Publication Date:
25 May 2010 (online)
Introduction
Thiocarbonylthio compounds consist mainly of thioesters, trithiocarbonates, xanthates, and dithiocarbamates. They undergo saponification, alcoholysis or aminolysis in the same way as carbonates, carbamates and carboxylic esters. Xanthates and dithiocarbamates concern vulcanization of rubber and in formulation of insecticides and fungicides for plant protection. Also, these compounds are used as agents for the reversible addition fragmentation chain transfer (RAFT) in controlled polymer synthesis. Thiocarbonylthio compounds can be achieved in moderate to high yield by heating a bis(thiocarbonyl) disulfide with an azo compound. [¹]
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Thang S.-H.Chono YK.Mayadunne RTA.Moad G.Rizzardo E. Tetrahedron Lett. 1999, 40: 2435 - 2
Binot G.Quiclet-Sire B.Saleh T.Zard SZ. Synlett 2003, 382 - 3
Fabre S.Vila X.Zard SZ. Chem. Commun. 2006, 4964 - 4
Quiclet-Sire B.Zard SZ. Tetrahedron Lett. 1998, 39: 9435 - 5
Tournier L.Zard SZ. Tetrahedron Lett. 2005, 46: 455 - 6
Grainger RS.Innocenti P. Angew. Chem. Int. Ed. 2004, 43: 3445 - 7
Bagal SK.Tournier L.Zard SZ. Synlett 2006, 1485 - 8
Corbet M.Ferjancic Z.Quiclet-Sire B.Zard SZ. Org. Lett. 2008, 10: 3579 - 9
Mercey G.Brégeon D.Gaumont A.-C.Levillain J.Gulea M. Tetrahedron Lett. 2008, 49: 6553 - 10
Moad G.Rizzardo E.Thang SH. Polymer 2008, 49: 1079