Synfacts 2010(4): 0411-0411  
DOI: 10.1055/s-0029-1219602
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart ˙ New York

Helicene and Double Helicene

Contributor(s): Timothy M. Swager, Brett VanVeller
Z. Wang, J. Shi, J. Wang, C. Li, X. Tian, Y. Cheng*, H. Wang*
Henan University, Kaifeng, Luoyang Normal University and Changchun Institute of Applied Chemistry, P. R. of China
Further Information

Publication History

Publication Date:
22 March 2010 (online)

Significance

A high-yield synthesis of three ­novel helicene compounds (3, 5 and 6) was developed. X-ray single-crystal structure analysis revealed multiple intermolecular short contacts and UV/Vis spectra indicate significant π-delocalization in double helicene 6, indicating potential in organic functional materials.