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Synfacts 2010(4): 0377-0377
DOI: 10.1055/s-0029-1219453
DOI: 10.1055/s-0029-1219453
Synthesis of Natural Products and Potential Drugs
© Georg Thieme Verlag
Stuttgart ˙ New York
Synthesis of Eudesmane Terpenes by C-H Activation
K. Chen, P. S. Baran*
The Scripps Research Institute, La Jolla, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
22. März 2010 (online)
Significance
The biomimetic synthesis of five oxidized members of the eudesmane family of terpenes has been achieved using chemoselective principles. Strain release, steric, and electronic properties were used to discriminate between different C-H environments for intermolecular oxidation.