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DOI: 10.1055/s-0029-1218759
Copper(II)-Catalyzed Esterification of Arenecarboxylic Acids with Aryl- and Vinyl-Substituted Trimethoxysilanes
Publikationsverlauf
Publikationsdatum:
29. April 2010 (online)
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Abstract
In this paper, the copper(II)-catalyzed esterification reaction of arenecarboxylic acids with aryl- or vinyl-substituted trimethoxysilanes is described. A series of aryltrimethoxysilanes and arenecarboxylic acids worked well under this procedure, affording aryl benzoate derivatives in moderate to good yields. Notably, trimethoxy(vinyl)silanes also worked well under this procedure giving a facile and versatile method to access vinyl benzoate derivatives.
Key words
copper(II) catalyzed - trimethoxysilanes - carboxylic acids - esters - silver(I) fluoride
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- Supporting Information
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References
For the transfer of phenyl from trimethoxy(phenyl)silane to copper(II), see refs 11c-e.
19The formation of a Ag(0) film was observed. We reasoned that Cu(0) is produced after reductive elimination and is then oxidized to Cu(II) by Ag(I).