RSS-Feed abonnieren
Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.
https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000131.xml
Synfacts 2010(1): 0082-0082
DOI: 10.1055/s-0029-1218500
DOI: 10.1055/s-0029-1218500
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Dicationic Pd(II)-Catalyzed Alkenylation of Glyoxylate with Vinylsilanes
K. Aikawa, Y. Hioki, K. Mikami*
Tokyo Institute of Technology, Japan
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
21. Dezember 2009 (online)
Significance
The authors described the enantioselective alkenylation of glyoxylate with vinylsilanes catalyzed by a chiral dicationic palladium BINAP complex. The desired allylic alcohols were obtained in good yields and excellent enantioselectivities. Furthermore, they applied this method to dienylation and trienylation with excellent enantioselectivities.