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Synfacts 2010(1): 0093-0093
DOI: 10.1055/s-0029-1218430
DOI: 10.1055/s-0029-1218430
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
A Facile Gold-Catalyzed Synthesis of Heterocycles from Propargyl Alcohols
A. Aponick*, C.-Y. Li, J. Malinge, E. F. Marques
University of Florida, Gainesville, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
21. Dezember 2009 (online)
Significance
Heterocycles such as furans, pyrroles, and thiophenes are widely spread cores found in biologically active natural products as well as pharmaceuticals and agrochemicals. The herein reported gold-catalyzed cycloisomerization of easily available propargylic alcohols provides a simple access to numerous derivatives of these important heterocycles.