Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml
Synfacts 2009(10): 1126-1126
DOI: 10.1055/s-0029-1217840
DOI: 10.1055/s-0029-1217840
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Copper-Catalyzed Kinetic Resolution of rac-α-Hydroxyphosphonates
Y. Demizu, A. Moriyama, O. Onomura*
Nagasaki University, Japan
Further Information
Publication History
Publication Date:
22 September 2009 (online)
Significance
This paper describes the nonenzymatic kinetic resolution of racemic α-hydroxyphosphonates catalyzed by copper Ph-BOX complex. The desired benzolylated products were obtained in good to excellent enantioselectivities and moderate yields.