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Synthesis 2009(11): 1909-1915
DOI: 10.1055/s-0029-1216789
DOI: 10.1055/s-0029-1216789
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Micellar Solution of Sodium Dodecyl Sulfate (SDS) Catalyzes Kabacknik-Fields Reaction in Aqueous Media
Further Information
Received
30 January 2009
Publication Date:
30 April 2009 (online)
Publication History
Publication Date:
30 April 2009 (online)
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Abstract
A new, convenient and high-yielding procedure for the one-pot synthesis of diethyl α-aminophosphonates from aldehydes, amines and diethyl phosphite (Kabacknik-Fields reaction) in SDS micellar solution in aqueous media is described. The synthesis of α-aminophosphonates in the present study represents a three-component reaction in which no intermediate formation of either an imine or α-hydroxyphosphonate was observed.
Key words
aldehydes - amines - α-aminophosphonates - micelles - sodium dodecyl sulfate - aqueous media
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