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Synfacts 2009(3): 0313-0313  
DOI: 10.1055/s-0028-1087711
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Indium-Catalyzed Friedel-Crafts Acylation Using Esters as Acylating Reagents

Contributor(s): Paul Knochel, Andreas J. Wagner
Y. Nishimoto, S. A. Babu, M. Yasuda, A. Baba*
Osaka University, Japan
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Publikationsverlauf

Publikationsdatum:
19. Februar 2009 (online)

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Significance

Herein, the authors describe the use of aryl- and alkylcarboxylic acid esters as acylating reagents in Friedel-Crafts reactions catalyzed by indium tribromide and using dimethylchlorosilane as saponifying reagent. The synthetic usefulness of this approach is demonstrated in the short synthesis of a salviasperanol intermediate.