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DOI: 10.1055/a-2317-3672
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Heterogenization of [Ru(bpy)3]Cl2 on Ordered Mesoporous Silica Materials for Photocatalytic Applications

Malik Sebbat
a   Université de Haute-Alsace (UHA), Université de Strasbourg, CNRS, Laboratoire d’Innovation Moléculaire et Application (LIMA), UMR 7042, 68100 Mulhouse, France
,
Anish Lazar
b   Université de Haute Alsace, CNRS, IS2M, UMR 7361, 68100 Mulhouse, France
c   Université de Strasbourg, 6700 Strasbourg, France
,
Claire Laurent
a   Université de Haute-Alsace (UHA), Université de Strasbourg, CNRS, Laboratoire d’Innovation Moléculaire et Application (LIMA), UMR 7042, 68100 Mulhouse, France
,
Christelle Despas
d   Université de Lorraine, CNRS, Laboratoire de Chimie Physique et Microbiologie pour les Matériaux et l’Environnement (LCPME), 54000 Nancy, France
,
Neus Vilà
d   Université de Lorraine, CNRS, Laboratoire de Chimie Physique et Microbiologie pour les Matériaux et l’Environnement (LCPME), 54000 Nancy, France
,
Alain Walcarius
d   Université de Lorraine, CNRS, Laboratoire de Chimie Physique et Microbiologie pour les Matériaux et l’Environnement (LCPME), 54000 Nancy, France
,
Nathan McClenaghan
e   Université de Bordeaux, CNRS, Institut des Sciences des Moléculaires (ISM), UMR 5255, 33405 Talence, France
,
Emmanuel Oheix
b   Université de Haute Alsace, CNRS, IS2M, UMR 7361, 68100 Mulhouse, France
c   Université de Strasbourg, 6700 Strasbourg, France
,
Bénédicte Lebeau∗
b   Université de Haute Alsace, CNRS, IS2M, UMR 7361, 68100 Mulhouse, France
c   Université de Strasbourg, 6700 Strasbourg, France
,
Morgan Cormier  ∗
a   Université de Haute-Alsace (UHA), Université de Strasbourg, CNRS, Laboratoire d’Innovation Moléculaire et Application (LIMA), UMR 7042, 68100 Mulhouse, France
,
Jean-Philippe Goddard∗
a   Université de Haute-Alsace (UHA), Université de Strasbourg, CNRS, Laboratoire d’Innovation Moléculaire et Application (LIMA), UMR 7042, 68100 Mulhouse, France
› Author AffiliationsThis study was supported by a public grant from the French Agence Nationale de la Recherche (ANR-21-CE07-044, PHOTOMATON2).
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Abstract

Herein, the preparation and characterization of three Ru-based heterogeneous photocatalysts supported on ordered mesoporous silica materials are reported. The photocatalytic activity of these catalysts was evaluated through oxidation, reduction, cycloaddition, and carboxylation reactions and their efficiencies are comparable to the parent [Ru(bpy)3]Cl2 under homogeneous conditions. These photocatalysts are efficiently recovered even after five reaction cycles offering new opportunities in sustainable chemistry.

Keywords

heterogeneous photocatalysis - ordered mesoporous silica - [Ru(bpy)3]Cl2 - sustainable chemistry

Supporting Information

    Supporting information for this article is available online at https://doi.org/10.1055/a-2317-3672.
  • Supporting Information


Publication History

Received: 10 April 2024

Accepted after revision: 30 April 2024

Accepted Manuscript online:
30 April 2024

Article published online:
11 June 2024

© 2024. Thieme. All rights reserved

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