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DOI: 10.1055/a-2192-9185
Lewis Base/3d Transition-Metal Cooperatively Catalyzed Asymmetric Reactions
Support was provided by the National Natural Science Foundation of China (grant nos. 21831007 and 22071229).
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Abstract
Lewis base/transition-metal cooperatively catalyzed asymmetric transformations have attracted extensive attention as they offer complementary catalytic systems within the realm of cooperative catalysis. Recently, the synergistic use of Lewis bases in combination with earth-abundant 3d metals has emerged as a fascinating prospect, presenting an opportunity to move away from the reliance on noble metals and to explore novel catalytic processes. In this Account, we highlight our recent achievements regarding the chemistry and synthetic utility of isothiourea (ITU) activated C1-ammonium enolates and N-heterocyclic carbene (NHC)-bound homoenolate equivalents in conjunction with 3d transition-metal activated electrophiles. The remarkable success in the stereoselective construction of carbon–carbon and carbon–heteroatom bonds has led to significant contributions to stereodivergent synthesis.
1 Introduction
2 ITU/Copper Cooperative Catalysis
3 NHC/Copper Cooperative Catalysis
4 NHC/Nickel Cooperative Catalysis
5 Conclusion
Key words
Lewis bases - 3d transition metals - cooperative catalysis - asymmetric catalysis - stereodivergent synthesisPublication History
Received: 08 September 2023
Accepted after revision: 16 October 2023
Accepted Manuscript online:
16 October 2023
Article published online:
01 December 2023
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