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Synthesis 2023; 55(19): 3113-3120
DOI: 10.1055/a-2096-6841
DOI: 10.1055/a-2096-6841
paper
Synthesis of N-Phenylcarbamate by C–N Coupling Reaction without Metal Participation
Autor*innen
The National Natural Science Foundation of China (Grant No. 21961038), and the Shanghai Cooperation Organization Science and Technology Partnership Program (No. 2022E01049).
Abstract
We have developed a new method for the synthesis of carbamates from amine and hydrazine formate. The reaction occurs in the presence of iodine and tert-butyl hydroperoxide, in which carbazates are produced via alkoxycarbonyl radical formation for cross-coupling reaction. The method exhibits broad functional group tolerance and affords a series of N-phenylcarbamates in moderate to good yields. Remarkably, our approach is metal free and utilizes cheap, readily available raw materials and relatively universal substrates.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2096-6841.
- Supporting Information (PDF) (opens in new window)
Publikationsverlauf
Eingereicht: 02. April 2023
Angenommen nach Revision: 22. Mai 2023
Accepted Manuscript online:
22. Mai 2023
Artikel online veröffentlicht:
27. Juni 2023
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