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Synlett 2022; 33(10): 907-912
DOI: 10.1055/a-1741-9000
DOI: 10.1055/a-1741-9000
synpacts
Multicomponent Reactions Among Alkyl Isocyanides, sp Reactants, and sp2 Carbon Cages
This work is supported by the U.S. Department of Energy (Grant No. DE-SC0020260), the Spanish Ministerio de Ciencia e Innovación (Grant No. PID2020-112762GB-I00), and the Generalitat de Catalunya (Grant No. 2017SGR629).
Abstract
We explored the reactivity and substrate scope of the reactions among an alkyl isocyanide, an sp-hybridized reactant (i.e. alkyne or allene), and a carbon cage, as a new approach to functionalize fullerenes and metallofullerenes. This account summarizes the key findings in our recent published work, and some original data for the reaction involving an isocyanide, allenes, and metallofullerene Lu3N@C80.
1 Introduction
2 Isocyanide-Induced Fullerene/EMF Reactions with Substituted Alkynes
3 Isocyanide-Induced Fullerene/EMF Reactions with Substituted Allenes
4 Conclusion
Publication History
Received: 22 December 2021
Accepted after revision: 16 January 2022
Accepted Manuscript online:
16 January 2022
Article published online:
10 February 2022
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