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CC BY 4.0 · Synthesis 2022; 54(03): 517-534
DOI: 10.1055/a-1657-2634
DOI: 10.1055/a-1657-2634
review
The Rise of Manganese-Catalyzed Reduction Reactions
We gratefully acknowledge the Max-Planck-Gesellschaft (Max Planck Society) for financial support.
Abstract
Recent developments in manganese-catalyzed reducing transformations—hydrosilylation, hydroboration, hydrogenation, and transfer hydrogenation—are reviewed herein. Over the past half a decade (i.e., 2016 to the present), more than 115 research publications have been reported in these fields. Novel organometallic compounds and new reduction transformations have been discovered and further developed. Significant challenges that had historically acted as barriers for the use of manganese catalysts in reduction reactions are slowly being broken down. This review will hopefully assist in developing this research area, by presenting a clear and concise overview of the catalyst structures and substrate transformations published so far.
1 Introduction
2 Hydrosilylation
3 Hydroboration
4 Hydrogenation
5 Transfer Hydrogenation
6 Conclusion and Perspective
Key words
manganese - reduction - homogeneous catalysis - hydrogenation - hydrosilylation - hydroboration - transfer hydrogenationPublication History
Received: 17 August 2021
Accepted after revision: 09 September 2021
Accepted Manuscript online:
29 September 2021
Article published online:
24 November 2021
© 2021. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by/4.0/)
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