Synthesis 2022; 54(03): 565-569
DOI: 10.1055/a-1648-2821
short review

Biaryl Synthesis via Electrooxidative Transition-Metal-Catalyzed C–H Activation

Jonas F. Goebel
,
Zhongyi Zeng
,
Lukas J. Gooßen
Funded by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany’s Excellence Strategy – EXC-2033–390677874 – RESOLV, SFB/TRR88 3MET, and FOR 982/1 UNODE. We thank the Bundesministerium für Bildung und Forschung (BMBF) and the state of Nordrhein-Westfalen (NRW) (Center of Solvation Science, ZEMOS).


Evonik Chair of Organic Chemistry

Abstract

The use of electricity as an inexpensive and waste-free oxidant opens up new opportunities for the development of sustainable C–H functionalization reactions. Herein we summarize recent advances in the synthesis of biaryls through electrooxidative processes involving transition-metal-catalyzed ortho-directed C–H activation. A particular focus is set on electrooxidative C–H/C–M couplings and dehydrogenative couplings.

1 Introduction

2 Electrooxidative C–H/C–M Couplings

3 Electrooxidative C–H/C–H Couplings

4 Conclusion and Outlook



Publication History

Received: 17 August 2021

Accepted after revision: 17 September 2021

Accepted Manuscript online:
17 September 2021

Article published online:
27 October 2021

© 2021. Thieme. All rights reserved

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