Synthesis of Side-Chain-Free Hydrazone-Linked Covalent Organic Frameworks through Supercritical Carbon Dioxide Activation

Shashini D. Diwakara; Gregory T. McCandless; Sampath B. Alahakoon; Ronald A. Smaldone

doi:10.1055/a-1477-5123

Organic Materials, Table of Contents

CC BY-NC-ND 4.0 · Organic Materials 2021; 03(02): 277-282
DOI: 10.1055/a-1477-5123

Energy Materials in the Age of Globalization

Original Article

Synthesis of Side-Chain-Free Hydrazone-Linked Covalent Organic Frameworks through Supercritical Carbon Dioxide Activation

Shashini D. Diwakara

^aThe Department of Chemistry and Biochemistry, The University of Texas at Dallas, Richardson, Texas 75080, United States

,

Gregory T. McCandless

^aThe Department of Chemistry and Biochemistry, The University of Texas at Dallas, Richardson, Texas 75080, United States

,

Sampath B. Alahakoon

^bInstitute for Combinatorial Advanced Research & Education (KDU-CARE), General Sir John Kotelawala Defence University Kandawala Rd, Ratmalana, 10390, Sri Lanka

,

Ronald A. Smaldone

^aThe Department of Chemistry and Biochemistry, The University of Texas at Dallas, Richardson, Texas 75080, United States

› Author Affiliations

Abstract

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Abstract

Supercritical carbon dioxide (scCO₂) activation provides milder conditions to process covalent organic frameworks (COFs) without compromising their crystallinity and porosity. To this end, three hydrazone COFs (TFPB-DHz COF, TFPT-DHz COF, Py-DHz COF) were synthesized with a terephthaloyl dihydrazide linker (DHz) which has no substituents. To date, the synthesis of hydrazone COFs without a narrow range of alkoxy linkers has not been possible. The scCO₂-activated hydrazone-linked COFs in this study were crystalline and had high surface areas (surface areas of TFPB-DHz COF, TFPT-DHz COF, and Py-DHz COF were 790, 1199, and 932 m²/g, respectively). This study shows the significance of using milder activation methods for making hydrazone-linked COF structures that were previously inaccessible.

Key words

covalent organic frameworks - hydrazones - supercritical carbon dioxide

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References

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