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CC BY-NC-ND 4.0 · Organic Materials 2021; 03(02): 245-253
DOI: 10.1055/a-1400-5581
Emerging Stars in Organic and Polymer Materials
Short Review

Asymmetric Organocatalysis with Chiral Covalent Organic Frameworks

Song-Chen Yu 
a   Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b   University of Chinese Academy of Sciences, Beijing 100049, China
,
Liang Cheng 
a   Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b   University of Chinese Academy of Sciences, Beijing 100049, China
c   Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Hangzhou 310024, China
,
Li Liu
a   Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b   University of Chinese Academy of Sciences, Beijing 100049, China
› Author Affiliations Funding Information This work was supported by the National Key Research and Development Program of China (2016YFA0602900) and Chinese Academy of Sciences.
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Abstract

Inspired by Mother Nature, the use of chiral covalent organic frameworks as heterogeneous asymmetric organocatalysts has arisen over the last decade as a new method in enantioselective synthesis. In this Short Review, sophisticated design of these polymeric materials and their application in asymmetric organocatalysis will be discussed.

Key words

chiral covalent organic frameworks - post-modification - asymmetric organocatalysis - enantioselective synthesis

Dedicated to Prof. emeritus Dong Wang on the occasion of his 80th birthday.




Publication History

Received: 14 December 2020

Accepted: 24 February 2021

Accepted Manuscript online:
25 February 2021

Article published online:
11 May 2021

© 2021. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes, or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/)

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