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Yoshikai, N. : 2023 Science of Synthesis, 2022/5: Base-Metal Catalysis 1 DOI: 10.1055/sos-SD-238-00277
Base-Metal Catalysis 1

1.15 Nickel-Catalyzed Nondirected C—H Functionalization

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Editor: Yoshikai, N. 

Authors: Chatani, N. ; Chemler, S. R. ; Chen, P. ; Dai, H.-X. ; Delcaillau, T.; Fujihara, T. ; Huang, J. ; Iwabuchi, Y. ; Kennedy-Ellis, J. J. ; Ko, C.; Koh, M. J. ; Lee, B. C.; Li, Y.; Lin, L.; Liu, G. ; Ma, D. ; Morandi, B. ; Nakao, Y. ; Ouyang, Y. ; Pang, X.; Qing, F.-L. ; Ren, Y. ; Sasano, Y. ; Shang, Y. ; Shou, J.-Y.; Shu, X.-Z. ; Su, W. ; Tobisu, M. ; Wang, C. ; Xiong, T. ; Xu, H.; Yang, F.; Yoshida, T.; Zhu, S. 

Title: Base-Metal Catalysis 1

Print ISBN: 9783132453807; Online ISBN: 9783132453821; Book DOI: 10.1055/b000000441

1st edition © 2023 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Reference Libraries



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

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Abstract

This chapter summarizes some selected examples of nickel-catalyzed nondirected C—H functionalization reactions. Nickel(0) complexes have been demonstrated to be effective for C—H alkylation and alkenylation reactions of arenes and hetarenes through a ligand-to-ligand hydrogen-transfer mechanism for C—H activation that is unique to nickel-catalyzed approaches. They also effect the C—H borylation of arenes and hetarenes. Some nickel(II) complexes are shown to catalyze cross-coupling-type transformations of hetarenes with organic electrophiles through C—H activation by nickel(II) intermediates.

Key words

base-metal catalysis - C—H activation - C—H alkylation - C—H alkenylation - C—H arylation - C—H alkynylation - C—H borylation - C—H functionalization - nickel catalysis
 
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