9 Decarbonylative/Decarboxylative Borylation
Buch
Herausgeber: Fernández, E.
Titel: Advances in Organoboron Chemistry towards Organic Synthesis
Print ISBN: 9783132429710; Online ISBN: 9783132429758; Buch-DOI: 10.1055/b-006-164898
2020 © 2020. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Organometallchemie;Chemische Labormethoden, Stöchiometrie
Science of Synthesis Reference Libraries
Übergeordnete Publikation
Titel: Science of Synthesis
DOI: 10.1055/b-00000101
Reihenherausgeber: Fürstner (Editor-in-Chief), A.; Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.
Typ: Mehrbändiges Werk
Abstract
Organoboron species are versatile building blocks and have been widely used in the synthesis of bioactive molecules, natural products, and organic materials. Accordingly, approaches to access such compounds have been widely explored. Carboxylic acids, which are ubiquitous and abundant organic feedstocks, can be transformed into their borylated counterparts via several different catalytic or stoichiometric approaches. In this review, decarboxylative borylation reactions, which form a carbon–boron bond with elimination of carbon dioxide, are detailed in terms of reaction conditions, substrate scope, and experimental procedures.
Schlüsselwörter
decarboxylative borylation - decarbonylative borylation - decarboxylation - borylation - carboxylic acids - boronic acids - boronic acid esters - boronates - light-induced reaction - photoredox catalysis - nickel catalysis - copper catalysis - redox-activated esters - N-hydroxyphthalimides- 2 E. C. Neeve,, S. J. Geier,, I. A. I. Mkhalid,, S. A. Westcott,, T. B. Marder,. Chem. Rev.. 2016; 116: 9091
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