1.8 Catalytic Reduction of Carbonates
Book
Editor: de Vries, J. G.
Title: Catalytic Reduction in Organic Synthesis 1
Print ISBN: 9783132406216; Online ISBN: 9783132406254; Book DOI: 10.1055/b-005-145236
1st edition © 2018 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry
Science of Synthesis Reference Libraries
Parent publication
Title: Science of Synthesis
DOI: 10.1055/b-00000101
Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Koch, G.; Molander, G. A.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.
Type: Multivolume Edition
Abstract
Carbonates are basic chemicals that are widely used in both industry and academia. Their reduction under either homogeneous or heterogeneous catalytic conditions generates formates, methanol, or methane. Carbonates can also act as a C1 building block for the reductive methylation of amines.
Key words
reduction - hydrogenation - homogeneous catalysis - heterogeneous catalysis - carbonates - alcohols - hydrolysis - formates - methylation- 3 Federsel C, Boddien A, Jackstell R, Jennerjahn R, Dyson PJ, Scopelliti R, Laurenczy G, Beller M. Angew. Chem. Int. Ed. 2010; 49: 9777
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