1.4. 2 Transfer Hydrogenation
Book
Editors: Cazin, C. ; Nolan, S.
Title: N-Heterocyclic Carbenes in Catalytic Organic Synthesis 1
Print ISBN: 9783132012813; Online ISBN: 9783132407633; Book DOI: 10.1055/b-004-132254
1st edition © 2017. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry
Science of Synthesis Reference Libraries
Parent publication
Title: Science of Synthesis
DOI: 10.1055/b-00000101
Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Koch, G.; Molander, G.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.
Type: Multivolume Edition
Abstract
The chapter describes the use of N-heterocyclic carbene (NHC) complexes of d-block metals for the transfer hydrogenation of C=O, C=C, C≡C, and C=N bonds, and nitro groups. Emphasis is placed on the most active metal–NHC combinations and those that incorporate valuable properties, including ease of use and inexpensive starting materials. The source of hydrogen is in most cases propan-2-ol, but formic acid/formate salts are also used.
Key words
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