1.5. 3 Brook Rearrangement as the Key Step in Domino Reactions
Book
Editor: Snyder, S. A.
Title: Applications of Domino Transformations in Organic Synthesis 1
Print ISBN: 9783131731319; Online ISBN: 9783132402522; Book DOI: 10.1055/b-003-128286
1st edition © 2016. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry
Science of Synthesis Reference Libraries
Parent publication
Title: Science of Synthesis
DOI: 10.1055/b-00000101
Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Koch, G.; Molander, G.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.
Type: Multivolume Edition
Abstract
The Brook rearrangement has lost its Cinderella status over the past twenty years since being embedded into cascade reaction sequences. The powerful formation of carbanions through silyl migration has been exploited for the development of many new methodologies and has been used as a key transformation in complex natural product syntheses. Now, the Brook rearrangement belongs to the common repertoire of synthetic organic chemists.
Key words
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