1.1.3 Arylation Using a Palladium(II) Catalyst

Abstract

This chapter focuses on the synthesis of biaryl C—C bonds via palladium(II)-catalyzed direct arylation of arenes with aryltin, arylboron, and arylsilicon reagents and aromatic carboxylic acids. Due to the ubiquity of C—H bonds in organic molecules, these methods represent an efficient and straightforward approach to biaryl C—C bonds. The chapter is organized based on the type of arylating reagent used.

Schlüsselwörter

C—H activation - arenes - arylation - biaryls - cross-coupling reactions - carboxylic acids - organometallic reagents - palladium catalysis

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