35.3.5.6 Synthesis of 1-Iodo-n-Heteroatom-Functionalized Alkanes (n ≥2) by Addition across C—X (X = O, N, S) or C—C Bonds (Update 2024)

J. P. Marciniszyn; M. Kretzschmar;   T. Gulder 

Abstract

This review updates the previous Science of Synthesis contributions on the synthesis of 1-iodo-n-heteroatom-functionalized alkanes (n ≥2) that are formed by addition across C—O (Section 35.3.5.2), C—N (Section 35.3.5.3), C—S (Section 35.3.5.4), or C—C bonds (Section 35.3.5.5). Methods reported between 2007 and 2023 are described, with a focus on the ring opening of three- or four-membered cyclic systems.

Schlüsselwörter

heterocycles - iodoalkanes - ring opening - hydroiodination - halogenation - transition-metal catalysis

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