20.2. 1.9 Synthesis of Alkanoic Acids Using Carbon Dioxide through Catalytic C—C Bond-Forming Reactions
Book
Editors: Wang, M. ; Drabowicz, J. ; Jiang, X. ; Campagne, J.-M.
Title: Knowledge Updates 2024/3
Online ISBN: 9783132457089; Book DOI: 10.1055/b000000969
early view © 2024 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry
Science of Synthesis Knowledge Updates
Parent publication
Title: Science of Synthesis
DOI: 10.1055/b-00000101
Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.
Type: Multivolume Edition
Abstract
In recent years, there has been growing interest in utilizing carbon dioxide as a feedstock for organic synthesis due to its abundance, low cost, and environmentally benign nature, with a particular focus on the catalytic synthesis of alkanoic acids from readily available starting materials via C–C bond formation. This review provides a comprehensive overview of this approach, covering the synthesis of alkanoic acids from alkyl (pseudo)halides, alkyl alcohol derivatives, isolable organometallic species, alkenes, and alkanes via C(sp3)–H bond activation. The versatility and practicality demonstrated for these methods underscores the significance of this approach in accessing valuable carboxylic acid derivatives from carbon dioxide.
Key words
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