9.14.5 Phospholes (Update 2024)

T. Tobrman 

Abstract

1H-Phospholes are five-membered heterocyclic compounds with a low degree of aromaticity. The low aromaticity of 1H-phospholes makes them a unique motif in terms of their applications in materials chemistry. On the other hand, 1H-phospholes have reactivity that contrasts with that of other five-membered heterocyclic compounds, such as furans, pyrroles, and thiophenes. This review summarizes procedures used for the preparation of substituted 1H-phospholes in the period 2012–2023. In addition, the synthesis of phospholide ions and (⁵-phospholyl complexes is described.

Schlüsselwörter

phospholes - cyclization - phospholide ions - transformation of substituents - heterocyclic compounds - reduction - Fagan–Nugent reaction

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