Campagne, J.-M.  et al.: 2024 Science of Synthesis, 2024/1: Knowledge Updates 2024/1 DOI: 10.1055/sos-SD-109-00525
Knowledge Updates 2024/1

9.14.5 Phospholes (Update 2024)

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Buch

Herausgeber: Campagne, J.-M. ; Donohoe, T. J.; Fürstner, A. ; Jiang, X. ; Wang, M.

Autoren: Cheng, J. ; Chowdhury, S. ; Harris, P. A. ; Li, X. ; Liu, M. ; Liao, L.; Song, Q. ; Tang, R.-Y. ; Tobrman, T. ; Wang, L.; Wu, X.-F. ; Ying, J. ; Yu, J.-S. ; Zhang, Y.

Titel: Knowledge Updates 2024/1

Online ISBN: 9783132457058; Buch-DOI: 10.1055/b000000967

Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Chemische Labormethoden, Stöchiometrie;Organometallchemie

Science of Synthesis Knowledge Updates



Übergeordnete Publikation

Titel: Science of Synthesis

DOI: 10.1055/b-00000101

Reihenherausgeber: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Typ: Mehrbändiges Werk

 


Abstract

1H-Phospholes are five-membered heterocyclic compounds with a low degree of aromaticity. The low aromaticity of 1H-phospholes makes them a unique motif in terms of their applications in materials chemistry. On the other hand, 1H-phospholes have reactivity that contrasts with that of other five-membered heterocyclic compounds, such as furans, pyrroles, and thiophenes. This review summarizes procedures used for the preparation of substituted 1H-phospholes in the period 2012–2023. In addition, the synthesis of phospholide ions and (5-phospholyl complexes is described.

 
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