5.1.13.3 Germylamines (Update 2020)

Abstract

This review describes the synthesis of compounds that have an organogermanium(IV) fragment (R¹ ₃Ge) attached to a formally anionic nitrogen-containing fragment (R² ₂N⁻). It is an update to the earlier Science of Synthesis contribution on these compounds (Section 5.1.13) and covers the literature published since 2003. The synthetic methods described include synthesis by metathesis, ligand exchange, and the oxidative addition of germylenes to different substrates. The synthesis of germylamines using heterocumulenes and the preparation of macrocyclic germylamines is also discussed.

Schlüsselwörter

germylamines - germanes - germanium compounds - macrocyclic ligands - nitrogen ligands - metathesis - halo compounds - lithium compounds

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