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Jiang, X. et al.: 2020 Science of Synthesis, 2020/3: Knowledge Updates 2020/3 DOI: 10.1055/sos-SD-105-00278
Knowledge Updates 2020/3

5.1.13.3 Germylamines (Update 2020)

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Book

Editors: Jiang, X.; Marschner, C.; Oestreich, M.; Wang, M.

Authors: An, K.; Arisetti, N.; Cheng, B.; Gao, W.-C. ; He, W.; Jiang, B. ; Krause, N.; Lu, J.-M.; Marschner, C.; Shao, L.-X.; Shi, T. ; Tan, Q. ; Tian, J.; Wang, T.; Wang, Z. ; Wei, W.; Weinert, C. S.; Zhang, H.-H.; Zhang, Q.-W.; Zhao, X.; Zhu, C.-F.

Title: Knowledge Updates 2020/3

Print ISBN: 9783132435643; Online ISBN: 9783132435667; Book DOI: 10.1055/b000000104

1st edition © 2020 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

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Abstract

This review describes the synthesis of compounds that have an organogermanium(IV) fragment (R1 3Ge) attached to a formally anionic nitrogen-containing fragment (R2 2N−). It is an update to the earlier Science of Synthesis contribution on these compounds (Section 5.1.13) and covers the literature published since 2003. The synthetic methods described include synthesis by metathesis, ligand exchange, and the oxidative addition of germylenes to different substrates. The synthesis of germylamines using heterocumulenes and the preparation of macrocyclic germylamines is also discussed.

Key words

germylamines - germanes - germanium compounds - macrocyclic ligands - nitrogen ligands - metathesis - halo compounds - lithium compounds
 
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