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Jiang, X. et al.: 2020 Science of Synthesis, 2020/3: Knowledge Updates 2020/3 DOI: 10.1055/sos-SD-105-00260
Knowledge Updates 2020/3

5.1.3 Product Subclass 3: Metalated Germanium Compounds

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Book

Editors: Jiang, X.; Marschner, C.; Oestreich, M.; Wang, M.

Authors: An, K.; Arisetti, N.; Cheng, B.; Gao, W.-C. ; He, W.; Jiang, B. ; Krause, N.; Lu, J.-M.; Marschner, C.; Shao, L.-X.; Shi, T. ; Tan, Q. ; Tian, J.; Wang, T.; Wang, Z. ; Wei, W.; Weinert, C. S.; Zhang, H.-H.; Zhang, Q.-W.; Zhao, X.; Zhu, C.-F.

Title: Knowledge Updates 2020/3

Print ISBN: 9783132435643; Online ISBN: 9783132435667; Book DOI: 10.1055/b000000104

1st edition © 2020 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

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Abstract

This review provides a summary of synthetic approaches to germanides. The described methods involve digermane cleavage, reduction of halogermanes, nucleophilic abstraction of silyl, germyl, or stannyl groups, hydrogermane deprotonation, nucleophilic addition to germylenes, and transmetalation. It covers literature from the 1950s until 2019.

Key words

anionic reagents - germanides - germanium compounds - germanes - lithium compounds
 
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