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Synthesis 2018; 50(24): 4765-4776
DOI: 10.1055/s-0037-1611278
DOI: 10.1055/s-0037-1611278
short review
Direct Trifluoromethylthiolation Reactions Involving Radical Processes
Further Information
Publication History
Received: 10 September 2018
Accepted after revision: 27 September 2018
Publication Date:
05 November 2018 (online)
Abstract
An overview of the most significant radical-based synthetic methods currently available for the preparation of trifluoromethylthiolated compounds is presented.
1 Introduction
2 Early Work: Photochemical Reactions Under UV Irradiation
2.1 Reactions Involving CF3SH
2.2 Reactions Involving CF3SCl
2.3 Reactions Involving CF3SSCF3
3 Reactions Involving a Nucleophilic SCF3 Reagent
3.1 Reactions with CuSCF3
3.2 Reactions with AgSCF3
4 Reactions Involving an Electrophilic SCF3 Reagent
4.1 Reactions Involving the Formation of an R• Radical
4.2 Reactions involving the formation of •SCF3 Radical
5 Conclusion
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