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Synthesis 2014; 46(10): 1355-1361
DOI: 10.1055/s-0033-1340905
special topic
© Georg Thieme Verlag Stuttgart · New York

Relay Catalytic Cascade Hydrosiloxylation and Asymmetric Hetero-Diels–Alder Reaction

Nan Li
Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. of China   Fax: +86(551)3606266   Email: gonglz@ustc.edu.cn
,
Dian-Feng Chen
Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. of China   Fax: +86(551)3606266   Email: gonglz@ustc.edu.cn
,
Pu-Sheng Wang
Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. of China   Fax: +86(551)3606266   Email: gonglz@ustc.edu.cn
,
Zhi-Yong Han
Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. of China   Fax: +86(551)3606266   Email: gonglz@ustc.edu.cn
,
Liu-Zhu Gong*
Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. of China   Fax: +86(551)3606266   Email: gonglz@ustc.edu.cn
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Publication History

Received: 27 January 2014

Accepted after revision: 12 February 2014

Publication Date:
17 March 2014 (online)

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Abstract

The hybrid gold(I)/Brønsted acid binary catalyst system enables enynes to participate in an asymmetric relay catalytic cascade intramolecular hydrosiloxylation and asymmetric hetero-Diels–Alder reaction with fluorenyl glyoxylate.

Key words

Diels–Alder reaction - enantioselectivity - silicon - heterocycles - enynes

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    for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
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Primary Data

    for this article are available online at http­://www.thieme-connect.com/ejournals/toc/synthesis and can be cited using the following DOI: 10.4125/pd0056th.
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